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The purpose of this study is to investigate the effect of the considerable Ag₂SO₄ content on the electrical and dielectric properties of (AgPO₃)_1−x(Ag₂SO₄)_x ion glass system as well as to extract thermodynamic parameters.

Glass samples of (AgPO₃)_1-x(Ag₂SO₄)_x with different mole ratios of Ag₂SO₄ [x = 0.00, 0.10,0.15,0.20 and 0.25] have been synthesized and used. X-ray diffraction and differential thermal analysis were used to investigate structural and thermal properties, and then the electrical characterizations of the bulk glasses were performed in different frequency and temperature range.

For different ratios of Ag₂SO₄ on AgPO₃, the bulk conductivity is enhanced with increasing the amount of Ag₂SO₄ until the composition of x = 0.20, after which the conductivity decreases. The general behavior of both ε’ and ε” decreases with increasing frequency and increases with increasing temperature. Complex impedance analysis studied by Z‘−Z’ and Cole–Cole plot at different temperatures revealed that bulk resistance decreases with temperature.

The calculated values of activation free energy, enthalpy and entropy change for different compositions of (AgPO₃)_1-x(Ag₂SO₄)_x showed an increase in activation energy and enthalpy when Ag₂SO₄ ratio is increased in (AgPO₃)_1-x(Ag₂SO₄)_x composition up to 20%, and then there is a decrease in their values at x = 25%, which may be explained based on non-bridging oxygen.